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804215 Sigma-Aldrich

[Ir{dFCF3ppy}2(bpy)]PF6

  • CAS Number 1092775-62-6

  • Empirical Formula (Hill Notation) C34H18F16IrN4P

  • Molecular Weight 1009.70

  •  PubChem Substance ID 329768852

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts, Photocatalysis
Quality Level   100
form   powder
reaction suitability   reagent type: catalyst
reaction type: Photocatalysis
SMILES string   FP(F)(F)(F)F.FC1=CC(F)=C(C2=[N]3C=C(C(F)(F)F)C=C2)C([Ir+]345([N]6=C(C7=CC=CC=[N]75)C=CC=C6)[N]8=C(C9=C(F)C=C(F)C=C94)C=CC(C(F)(F)F)=C8)=C1.[F-]
InChI   1S/2C12H5F5N.C10H8N2.F5P.FH.Ir/c2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-6(2,3,4)5;;/h2*1-2,4-6H;1-8H;;1H;/q;;;;;+1/p-1
InChI key   DZIQZTFRUCLPRL-UHFFFAOYSA-M

Description

Application

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

Packaging

50 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Photoredox Iridium Catalyst for Single Electron Transfer (SET) Cross-Coupling

C(sp2)- and C(sp)-hybridized coupling reactions are established catalytic approaches. However, multi-step C(sp3)- and C(sp2)-coupling reactions of boronic acids and related derivatives are still limi...
Keywords: Asymmetric synthesis, Catalysis, Coupling reactions, Cross couplings, Eliminations, Reductive eliminations, Transmetalation

Professor and Product Portal - Gary Molander Group

From our library of Articles, Sigma-Aldrich presents Professor and Product Portal - Gary Molander Group
Keywords: Catalysis, Coupling reactions, Cross couplings, Transmetalation

Peer-Reviewed Papers
15

References

Related Products

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Product #

Description

Add to Cart

901368 [Ir(dFppy)2(dtbbpy)]PF6
901409 [Ir(dF(Me)ppy)2(dtbbpy)]PF6
902217 Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902225 Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%
904694 Ir(p-CF3-ppy)3, ≥95%
905917 (Ir[Me(Me)ppy]2(dtbpy))PF6
908568 [Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6, ≥95%
908703 [Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

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