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804282 Sigma-Aldrich

SPhos Pd G4

  • CAS Number 1599466-87-1

  • Empirical Formula (Hill Notation) C40H50NO5PPdS

  • Molecular Weight 794.29

  •  PubChem Substance ID 329768857

  •  NACRES NA.22

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Properties

Related Categories Buchwald 4th Generation Palladacycles, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,
Quality Level   100
assay   95%
form   powder
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Cross Couplings
SMILES string   CNC1=C(C2=C([Pd]OS(=O)(C)=O)C=CC=C2)C=CC=C1.COC3=CC=CC(OC)=C3C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6
InChI   1S/C26H35O2P.C13H12N.CH4O3S.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h9-11,16-21H,3-8,12-15H2,1-2H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key   ISSWOKPFLWDXSU-UHFFFAOYSA-M

Description

General description

SPhos Pd G4 is a versatile 4th generation palladium precatalyst developed by Buchwald group.

Packaging

1 g in glass bottle

100 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

G3 and G4 Buchwald Precatalysts

Visit Stephen Buchwald’s Professor Product Portal for more information on palladium precatalysts and products offered by the Buchwald Laboratory.
Keywords: Aminations, Arylations, Catalysis, Coupling reactions, Cross couplings, Deprotonations, Hydroxylations, Ligands, Pharmaceutical, Solvents, Suzuki-Miyaura coupling

Stephen Buchwald Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stephen Buchwald Group – Professor Product Portal
Keywords: Aminations, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Coupling reactions, Cross couplings, Fluorinations, Ligands, Solvents, transformation

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903663 t-BuDavePhos Pd G4

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