• USA Home
  • 804398 - [(TMEDA)Ni(o-tolyl)Cl]

EMAIL THIS PAGE TO A FRIEND
804398 Sigma-Aldrich

[(TMEDA)Ni(o-tolyl)Cl]

95%

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel, Non-Precious Metal Catalysis
Quality Level   100
assay   95%
form   powder
  powder
reaction suitability   reagent type: catalyst
SMILES string   CC1=CC=CC=C1[Ni]Cl.CN(C)CCN(C)C
InChI   1S/C7H7.C6H16N2.ClH.Ni/c1-7-5-3-2-4-6-7;1-7(2)5-6-8(3)4;;/h2-5H,1H3;5-6H2,1-4H3;1H;/q;;;+1/p-1
InChI key   NMLMESVZRUMFAE-UHFFFAOYSA-M

Description

Application

Effective precatalyst for a variety of nickel-catalyzed transformations, including Suzuki-Miyaura, Buchwald-Hartwig and other cyclizations and oxidative couplings.

Packaging

100 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

Please Enter a Lot Number
Protocols & Articles

Articles

Abigail Doyle Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Abigail Doyle Group – Professor Product Portal
Keywords: Alkylations, Asymmetric synthesis, Catalysis, Coupling reactions, Cross couplings, Deprotonations, Eliminations, Fluorinations, Ligands, Positron Emission Tomography, Reductive eliminations, Research areas

Broad Application Doyle Nickel Precatalyst

In modern transition metal-catalyzed coupling reactions, palladium has asserted its place as a dominant impetus. In comparison to previously used nickel catalysts, Pd(0) has been a proven precatalyst...
Keywords: Catalysis, Coupling reactions, Cyclizations, Oxidative additions

Peer-Reviewed Papers
15

References

Related Products

related product

Product #

Description

Add to Cart

902993 (BPhen)Ni(OAc)2.xH2O
902985 (Bathocuproine)NiBr2
903000 [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine] nickel (II) dichloride
903019 [4,4′-Dimethyl-2,2′-bipyridine]nickel(II) dichloride hydrate, ≥95%
904937 2,6-Bis(N-pyrazolyl)pyridine nickel (II) dichloride, ≥95% anhydrous basis
905070 [(TEEDA)Ni(o-tolyl)Cl], ≥95%
907111 2,6-bis(N-pyrazolyl)pyridine nickel(II) bromide
911534 (4,4′-dMeObpy)NiCl2
911844 (Me4Phen)NiCl2
911984 (2,2′-Bipyridine)diiodonickel(II)
913014 [1,3-Bis(diphenylphosphino)propane]dibromonickel(II), ≥95%
913278 [1,2-Bis(diphenylphosphino)ethane]dibromonickel(II), ≥95%
913154 1,10-Phenanthroline nickel (ll) dibromide
916129 1,10-Phenanthroline nickel (ll) dichloride

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?