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804452 Sigma-Aldrich

Potassium 3-ethoxycarbonylbenzoyltrifluoroborate

  • CAS Number 1622923-42-5

  • Empirical Formula (Hill Notation) C10H9BF3KO3

  • Molecular Weight 284.08

  •  PubChem Substance ID 329768873

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Properties

Related Categories Acyl Trifluoroborate Salts, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Trifluoroborate Salts More...
InChI Key   WJLIBYVPNAKYHP-UHFFFAOYSA-N
form   powder

Description

Application

Acyltrifluroborates (KAT′s) are bench, air, and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group.

Packaging

1 g in glass bottle

Other Notes

Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation

Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water

Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation, Properties, and Reactivities

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles

Articles

Jeffrey Bode Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Jeffrey Bode Group – Professor Product Portal
Keywords: Annulations, Asymmetric synthesis, Catalysis, Cross couplings, transformation

Peer-Reviewed Papers
15

References

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