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805009 Sigma-Aldrich

[(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2

Synonym: (Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer

  • CAS Number 1779569-01-5

  • Empirical Formula (Hill Notation) C26H30Cl2Pd2

  • Molecular Weight 626.26

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
Quality Level   100
assay   95%
form   powder
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
mp   166 °C
SMILES string   CC(C)(C)[C@H]1[C@H]2[C@H](CCCC2)CC1.C[Pd]Cl.C[Pd]Cl.CC(C)(C)c3ccc4c3cccC4

Description

Application

The following palladium dimer is a precatalyst scaffold for cross-coupling reactions originally reported by the Hazari research group. When used with an selected ligand, the precatalyst exhibits superior activity over a wide array of cross-coupling reactions and under a variety of conditions.

Packaging

500 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

1-tBu-Indenyl Supported Palladium Precatalysts for Cross-Coupling

The Hazari Group has developed an improved palladium precatalyst scaffold for a wide range of cross-coupling reactions.  This system combines fast activation from Pd(II) to the active monoligated Pd(...
Keywords: Coupling reactions, Cross couplings, Ligands, transformation

Nilay Hazari Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Nilay Hazari Group - Professor Product Portal
Keywords: Arylations, Catalysis, Cross couplings, Ligands

Stephen Buchwald Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stephen Buchwald Group – Professor Product Portal
Keywords: Aminations, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Coupling reactions, Cross couplings, Fluorinations, Ligands, Solvents, transformation

Peer-Reviewed Papers
15

References

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