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805238 Sigma-Aldrich

FK 102 Co(II) PF6 salt

Synonym: Greatcell Solar®, tris(2-(1H-pyrazol-1-yl)pyridine)cobalt(II) di[hexafluorophosphate]

  • CAS Number 1392221-69-0

  • Empirical Formula (Hill Notation) C24H21CoF12N9P2

  • Molecular Weight 784.35

  •  MDL number MFCD29037024

  •  PubChem Substance ID 329768922

  •  NACRES NA.23

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Properties

Related Categories Alternative Energy, Dye Sensitized Solar Cell (DSSC) Materials, Hole Conductor Cobalt Dopants, Materials Science, Organic Photovoltaic (OPV) Materials,
Quality Level   100
assay   98%
form   powder
mp   362 °C
SMILES string   F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.N1(C2=NC=CC=C2)N=CC=C1.C3(N4C=CC=N4)=CC=CC=N3.C5(N6C=CC=N6)=CC=CC=N5.[Co+2]
InChI   1S/3C8H7N3.Co.2F6P/c3*1-2-5-9-8(4-1)11-7-3-6-10-11;;2*1-7(2,3,4,5)6/h3*1-7H;;;/q;;;+2;2*-1
InChI key   MLELXRWOHQBFBO-UHFFFAOYSA-N

Description

Application

Use this cobalt complexes to increase photovoltages of liquid electrolyte cells substantially or to achieve ultrahigh performance with solid state photovoltaic devices.
FK102 cobalt complexes offer guaranteed performance, high reproducibility, consistent results, and are of highest purity. In comparison to triiodide-based redox electrolytes, cobalt complexes in general increase photovoltages and particularly at lower light levels (e.g. for indoor applications), significantly increase device power output.
Recommended use:
In liquid-based electrolytes: typically 0.15-0.2M of Co(II) and ca. 0.05M Co(II)
In solid-state photovoltaic cells: up to 10 weight % added to the hole transport material system.

Packaging

5 g in poly bottle

Legal Information

Product of Greatcell Solar®.

Greatcell Solar is a registered trademark of Greatcell Solar

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Perovskite Solar Cells

School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia, USA
Keywords: Crystallization, Degradations, Deposition, Materials Science, Nucleic acid annealing, Photovoltaics, Recombination, Reductions, Renewable energy, Solar cells

Recent Advances in Hybrid Halide Perovskites-based Solar Cells

Kuppuswamy Kalyanasundaram, Shaik. M. Zakeeruddin, Michaël Grätzel* Laboratory for Photonics and Interfaces (LPI) Swiss Federal Institute of Technology at Lausanne (EPFL) 1015 Lausanne, Switzerland *...
Kuppuswamy Kalyanasundaram, Shaik. M. Zakeeruddin, Michaël Grätzel
Material Matters, 2016, 11.1, 3
Keywords: Absorption, Atomic layer deposition, Capillary electrophoresis, Degradations, Deposition, Diffusion, Environmental, Infrared spectroscopy, Nanomaterials, Nanotubes, Nucleic acid annealing, Recombination, Semiconductor, Separation, Sol-gel, Solar cells, Solvents, Spectroscopy, Spin coating, Substitutions

Ruthenium-based dyes for Dye-sensitized Solar Cells

Dye-sensitized Solar Cells (DSCs) are 3rd generation solar cells combining the promise of high efficiency with low production costs. While present-day DSCs provide light-to-electricity conversion of ...
Dr. Hans Desilvestro and Dr. Yanek Hebting

Dyesol Ltd., 3 Dominion Place, Queanbeyan NSW 2620 AUSTRALIA
Keywords: Absorption, Calorimetry, Capillary electrophoresis, Ligands, Oxidations, Photosynthesis, Recombination, Reductions, Separation, Solar cells

Ultra-High Efficiency Perovskite-Perovskite Tandem Solar Cells

Chemistry and Nanoscience Center, National Renewable Energy Laboratory, Golden, Colorado 80401, USA *Email: Kai.Zhu@nrel.gov
Zhen Li and Kai Zhu*
Material Matters, 2018, 13.1
Keywords: Absorption, Adhesion, Degradations, Deposition, Diffraction, Evaporation, Infrared spectroscopy, Nanotubes, Nucleic acid annealing, Oxidations, Photovoltaics, Recombination, Renewable energy, Semiconductor, Solar cells, Solvents, Ultraviolet-Visible spectroscopy, X-Ray diffraction

Peer-Reviewed Papers
15

References

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