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807869 Sigma-Aldrich

P(o-Tolyl)3-Pd-G2 GT capsule

  • Empirical Formula (Hill Notation) C33H31ClNPPd

  • Molecular Weight 614.45

  •  MDL number MFCD22417213

  •  PubChem Substance ID 329768751

  •  NACRES NA.22

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Properties

Related Categories Buchwald 2nd Generation Palladacycles, Buchwald Ligands, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis,
Quality Level   100
form   capsule
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Cross Couplings
InChI   1S/C21H21P.C12H10N.ClH.Pd/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h4-15H,1-3H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1
InChI key   MNKLPYUHUVVRNW-UHFFFAOYSA-M

Description

General description

The product is a second generation (G2) Buchwald precatalyst. The G2 precatalysts are improved form of G1 precatalysts. They are formed by substituting the phenethylamine based backbone of the G1 complex with a biphenyl-based ligand. This modification leads to the formation of active Pd species at room temperature with weak bases. Buchwald precatalysts are air, moisture and thermally-stable. It is highly useful in cross-coupling reactions.

Application

Convenient dosable form of P(o-Tolyl)3-Pd-G2

Packaging

5 ea in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Buchwald GT Capsules for Cross-Coupling

The advent of the Buchwald portfolio of ligands and complexes for cross-coupling reactions in the past decade has greatly advanced the ease of performing this transformation. The catalysts are highly...
Keywords: Catalysis, Coupling reactions, Cross couplings, Ligands, transformation

Stephen Buchwald Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stephen Buchwald Group – Professor Product Portal
Keywords: Aminations, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Coupling reactions, Cross couplings, Fluorinations, Ligands, Solvents, transformation

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