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808016 Sigma-Aldrich

(R,S,S)-Elenor Amination Reagent

Synonym: 3H-3a,6-Methano-2,1-benzisothiazole-1(4H)-carboxamide, tetrahydro-N-hydroxy-8,8-dimethyl-, 2,2-dioxide, (3aR,6S,7aS)-

  • CAS Number 188845-76-3

  • Empirical Formula (Hill Notation) C11H18N2O4S

  • Molecular Weight 274.34

  •  PubChem Substance ID 329769051

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Properties

Quality Level   100
form   powder
storage temp.   2-8°C
SMILES string   O=C(N1S(C[C@@]2(C3(C)C)CC[C@@]3([H])C[C@]12[H])(=O)=O)NO
InChI   1S/C11H18N2O4S/c1-10(2)7-3-4-11(10)6-18(16,17)13(8(11)5-7)9(14)12-15/h7-8,15H,3-6H2,1-2H3,(H,12,14)/t7-,8-,11-/m0/s1
InChI key   FYSORZDAOUCPGD-LAEOZQHASA-N

Description

Application

The following hydroxyamide is a chiral electrophilic nitroso reagent for the transfer of nitrogen to enol ethers. This methology was reported by the Read de Alaniz Group, is a mild approach that can be performed at room temperature and in the presence of air.

Packaging

1 g in glass bottle

Other Notes

Asymmetric Electrophilic α-Amination of Silyl Enol Ether Derivatives via the Nitrosocarbonyl Hetero-ene Reaction

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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