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809128 Sigma-Aldrich

(R)-Ph-Quinox

Synonym: 2-[(4R)-4,5-dihydro-4-phenyl-2-oxazolyl]quinoline

  • CAS Number 220108-54-3

  • Empirical Formula (Hill Notation) C18H14N2O

  • Molecular Weight 274.32

  •  PubChem Substance ID 329769140

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Other Ligands More...
Quality Level   100
assay   ≥95%
form   powder
reaction suitability   reagent type: catalyst
SMILES string   C1(C2=CC=C(C=CC=C3)C3=N2)=N[C@H](C4=CC=CC=C4)CO1
InChI   1S/C18H14N2O/c1-2-6-13(7-3-1)17-12-21-18(20-17)16-11-10-14-8-4-5-9-15(14)19-16/h1-11,17H,12H2/t17-/m0/s1
InChI key   OIFADUQNTPUCKK-KRWDZBQOSA-N

Description

General description

(R)-Ph-Quinox-Pd-alkyl complex contains (R)-Ph-quinox (2-[(4R)-4,5-dihydro-4-phenyl-2-oxazolyl]quinolone) as a chiral ligand.

Application

This ligand has been proven effective in the enantioselective diamination of alkenes.

Packaging

250 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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901216 (S)-Ph-quinox, ≥95%

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