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809527 Sigma-Aldrich

N-Cyclohexyl-2,6-bis(1-methylethyl)-Benzenamine

Synonym: N-Cyclohexyl-2,6-diisoproylaniline, CyAnH

  • CAS Number 1338363-23-7

  • Empirical Formula (Hill Notation) C18H29N

  • Molecular Weight 259.43

  •  PubChem Substance ID 329769166

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Properties

Related Categories Baran Hindered Amines, Building Blocks, Chemical Synthesis, Organic Building Blocks
InChI Key   YDWZEQMCJKBGTO-UHFFFAOYSA-N
form   crystals
mp   67-72 °C

Description

Packaging

1 g in glass bottle

Application

Deprotonating CyAnH to form the lithiated base LiCyAn, provides a critical reagent in the α, β-dehydrogenation of enones and other unsaturated systems under palladium catalysis, as reported by Newhouse and coworkers.

General description

N-Cyclohexyl-2,6-bis(1-methylethyl)-benzenamine is a hindered monodentate aniline derivative.

Other Notes

Amide α,β-Dehydrogenation Using Allyl-Palladium Catalysis and a Hindered Monodentate Anilide

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

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Protocols & Articles
Peer-Reviewed Papers
15

References

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