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88508 Sigma-Aldrich

Bis[tris(3-(heptadecafluorooctyl)phenyl)phosphine]palladium(II) dichloride

≥95% (31P-NMR)

Synonym: Bis[tris(3-(perfluorooctyl)phenyl)phosphine]palladium(II) dichloride

  • CAS Number 326475-45-0

  • Empirical Formula (Hill Notation) C84H24Cl2F102P2Pd

  • Molecular Weight 3210.20

  •  MDL number MFCD03791111

  •  PubChem Substance ID 24889106

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Properties

assay   ≥95% (31P-NMR)
SMILES string   Cl[Pd]Cl.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)c1cccc(c1)P(c2cccc(c2)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c3cccc(c3)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)c4cccc(c4)P(c5cccc(c5)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c6cccc(c6)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

Description

Application

Catalyst for Stille and Suzuki couplings in Fluorous Biphase Systems (FBS)

Other Notes

Perfluoro-tagged Pd complexes as catalysts for Stille couplings in a fluorous biphase system, palladium-catalyzed Suzuki couplings.

Safety & Documentation

Safety Information

Personal Protective Equipment 
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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