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  • 88718 - (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

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88718 Sigma-Aldrich

(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

≥97%

Synonym: (2S)-1-[(1S)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS), (S)-(R)-Josiphos, Josiphos SL-J001-2

  • CAS Number 162291-02-3

  • Empirical Formula (Hill Notation) C36H44FeP2 · C2H5OH

  • Molecular Weight 640.60

  •  MDL number MFCD00800285

  •  PubChem Substance ID 24888986

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Josiphos Ligands, Privileged Ligands and Complexes,
description   ethanol adduct
InChI Key   HGTBZFMPHBAUCQ-WLOLSGMKSA-N
assay   ≥97%
optical purity   ee: ≥99%

Description

General description

sold in collaboration with Solvias AG

Packaging

1, 5 g in glass bottle

100, 500 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles

Articles

Solvias® Ligand Portfolio for Enantioselective Hydrogenation

Today's Solvias Ligand Portfolio has its roots in the development of the Josiphos ligands and the successful implementation in the (S)-metolachlor process—the largest industrial enantioselective manu...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 14.
Keywords: Alkylations, Aminations, Asymmetric catalysis, Asymmetric synthesis, Building blocks, Catalysis, Coupling reactions, Crystallization, Grignard Reaction, Heck Reaction, Herbicides, Hydroformylations, Hydrogenations, Infrared spectroscopy, Kumada Coupling, Ligands, Michael Addition, Reductions, Supercritical fluid chromatography

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