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  • 88719 - (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

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88719 Sigma-Aldrich

(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

≥97%

Synonym: (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS), Josiphos SL-J002-1

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Josiphos Ligands, Privileged Ligands and Complexes,
InChI Key   STAGMXYQPGLLTD-GHVWMZMZSA-N
assay   ≥97%
optical purity   ee: ≥99%

Description

General description

(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-tBu) is a chiral ferrocenyl diphosphine ligand.

sold in collaboration with Solvias AG

Application

It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.

Packaging

1, 5 g in glass bottle

100, 500 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

Solvias Ferrocenyl-Based Ligands

Solvias AG has demonstrated the incredible utility of chiral ferrocenyl diphosphine ligands in a wide range of reaction paradigms ranging from hydrogenation1 to the aldol reaction2 to hydroboration.3...
Aldrich ChemFiles 2006, 6.8, 12.
Keywords: Addition reactions, Asymmetric synthesis, Catalysis, Chemfiles, Grignard Reaction, Hydrogenations, Ligands, Type

Solvias® Ligand Portfolio for Enantioselective Hydrogenation

Today's Solvias Ligand Portfolio has its roots in the development of the Josiphos ligands and the successful implementation in the (S)-metolachlor process—the largest industrial enantioselective manu...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 14.
Keywords: Alkylations, Aminations, Asymmetric catalysis, Asymmetric synthesis, Building blocks, Catalysis, Coupling reactions, Crystallization, Grignard Reaction, Heck Reaction, Herbicides, Hydroformylations, Hydrogenations, Infrared spectroscopy, Kumada Coupling, Ligands, Michael Addition, Reductions, Supercritical fluid chromatography

Related Content

Solvias Chiral Phosphine Ligands - Toolkit for Asymmetric Catalysis

Sigma-Aldrich, in collaboration with Solvias, is proud to present the Chiral Ligands Kit – the ultimate toolkit for asymmetric catalysis!
Keywords: Asymmetric catalysis, Asymmetric synthesis, Catalysis, Individual protein Immunoprecipitation, Ligands

Peer-Reviewed Papers
15

References

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