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  • 88720 - (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

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88720 Sigma-Aldrich

(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

≥97%

Synonym: (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS), Josiphos SL-J002-2

  • CAS Number 277306-29-3

  • Empirical Formula (Hill Notation) C32H40FeP2

  • Molecular Weight 542.45

  •  MDL number MFCD01074443

  •  PubChem Substance ID 24888988

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Josiphos Ligands, Privileged Ligands and Complexes,
assay   ≥97%
optical activity   [α]20/D +410±15°, c = 0.5 in chloroform
optical purity   ee: ≥99%
storage temp.   room temp
SMILES string   [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C(C)(C)C)C(C)(C)C
InChI   1S/C27H35P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/m0../s1
InChI key   STAGMXYQPGLLTD-FGJQBABTSA-N

Description

General description

sold in collaboration with Solvias AG

Packaging

1 g in glass bottle

100, 500 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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