• USA Home
  • 88733 - (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

EMAIL THIS PAGE TO A FRIEND
88733 Sigma-Aldrich

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

≥97%

Synonym: (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene (acc to CAS), Josiphos SL-J009-1

Purchase

Description

Packaging

1, 5 g in glass bottle

100, 500 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Application

It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates.

General description

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (CyPF-tBu) is a chiral ferrocenyl diphosphine ligand.

sold in collaboration with Solvias AG

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Solvias® Ligand Portfolio for Enantioselective Hydrogenation

Today's Solvias Ligand Portfolio has its roots in the development of the Josiphos ligands and the successful implementation in the (S)-metolachlor process—the largest industrial enantioselective manu...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 14.
Keywords: Alkylations, Aminations, Asymmetric catalysis, Asymmetric synthesis, Building blocks, Catalysis, Coupling reactions, Crystallization, Grignard Reaction, Heck Reaction, Herbicides, Hydroformylations, Hydrogenations, Infrared spectroscopy, Kumada Coupling, Ligands, Michael Addition, Reductions, Supercritical fluid chromatography

Related Content

Solvias Chiral Phosphine Ligands - Toolkit for Asymmetric Catalysis

Sigma-Aldrich, in collaboration with Solvias, is proud to present the Chiral Ligands Kit – the ultimate toolkit for asymmetric catalysis!
Keywords: Asymmetric catalysis, Asymmetric synthesis, Catalysis, Individual protein Immunoprecipitation, Ligands

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?