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89025 Sigma-Aldrich

Copper(I) thiophenolate

≥98.0% (RT)

Synonym: Copper(I) thiophenoxide, PhSCu, Phenylthiocopper(I), Thiophenol copper(I) salt

  • CAS Number 1192-40-1

  • Linear Formula C6H5SCu

  • Molecular Weight 172.71

  •  Beilstein/REAXYS Number 3709171

  •  MDL number MFCD00064893

  •  PubChem Substance ID 24889167

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper Catalysts More...
Quality Level   100
assay   ≥98.0% (RT)
reaction suitability   reagent type: catalyst
mp   280 °C (dec.) (lit.)
SMILES string   [Cu]Sc1ccccc1
InChI   1S/C6H6S.Cu/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
InChI key   PNNJYDODNCALKD-UHFFFAOYSA-M

Description

Packaging

25 g in glass bottle

Application

Reagents used as the source of nucleophilic phenyl sulfide for preparation of lithiumalkyl(phenylthio)cuprates and organophosphinecopper(I) phenylthiolatecomplexes

Other Notes

Reagent for the simple preparation of lithium (phenylthio)alkyl-cuprates from lithium alkyls, used for conjugate addition to α,β-enones

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3263 8 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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