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900276 Sigma-Aldrich

MorDalPhos Pd G4

  • CAS Number 2230788-66-4

  • Empirical Formula (Hill Notation) C44H57N2O4PPdS

  • Molecular Weight 847.39

  •  PubChem Substance ID 329769797

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Properties

Related Categories Buchwald 4th Generation Palladacycles, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling More...
Quality Level   100
form   powder
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Cross Couplings
functional group   phosphine
storage temp.   room temp
SMILES string   CNC1=C(C=CC=C1)C2=C(C=CC=C2)[Pd]OS(C)(=O)=O.C3(N4CCOCC4)=CC=CC=C3P([C@@]56CC(C[C@@H]7C6)CC(C7)C5)[C@@]89C[C@H](C[C@@H]%10C9)C[C@H](C%10)C8
InChI   1S/C30H42NOP.C13H12N.CH4O3S.Pd/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h1-4,21-26H,5-20H2;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1/t21-,22?,23?,24-,25?,26?,29-,30-,33?;;;
InChI key   VWMHZTMMTNRWLL-GYEYKPDQSA-M

Description

Application

A powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

G3 and G4 Buchwald Precatalysts

Visit Stephen Buchwald’s Professor Product Portal for more information on palladium precatalysts and products offered by the Buchwald Laboratory.
Keywords: Aminations, Arylations, Catalysis, Coupling reactions, Cross couplings, Deprotonations, Hydroxylations, Ligands, Pharmaceutical, Solvents, Suzuki-Miyaura coupling

Stephen Buchwald Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stephen Buchwald Group – Professor Product Portal
Keywords: Aminations, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Coupling reactions, Cross couplings, Fluorinations, Ligands, Solvents, transformation

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