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900421 Sigma-Aldrich

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate

≥95%

Synonym: 3,6-Bis(1,1-dimethylethyl)-10-phenyl-9-(2,4,6-trimethylphenyl)-acridinium tetrafluoroborate, 3,6-Di-tert-butyl-9-(2,4,6-trimethylphenyl)-10-phenylacridinium tetrafluoroborate

  • CAS Number 1810004-87-5

  • Empirical Formula (Hill Notation) C36H40BF4N

  • Molecular Weight 573.51

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Properties

Related Categories Acridinium Catalysts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Photocatalysis
Quality Level   100
assay   ≥95%
form   powder or crystals
mp   277.2 °C
reaction suitability   reagent type: catalyst
reaction type: Photocatalysis

Description

Application

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate is an acridium-based photocatalyst that can be an alternative to transition-metal-based photocatalysts due to its higher chemical stability and attenuated redox potential.

When employed with TEMPO, this acridinium photocatalyst promotes the site-selective amination of a variety of simple and complex aromatics with heteroaromatic azoles. When ammonium carbamate is used as the amine, anilines can be achieved directly.

Packaging

100 mg in glass insert

Other Notes

Site-selective arene C-H amination via photoredox catalysis

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

David Nicewicz Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents David Nicewicz Group - Professor Product Portal
Keywords: Addition reactions, Catalysis, Cycloadditions, Hydroaminations, Infrared spectroscopy, Oxidations

Peer-Reviewed Papers
15

References

Related Products

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900693 9-Mesityl-1,3,6,8-tetramethoxy-10-phenylacridin-10-ium tetrafluoroborate, 95%
905194 10-Ethyl-3,7,8-trimethyl-benzo[g]pteridine-2,4(3H,10H)-dione, ≥95%
906115 2,7-Dibromoacridone
909033 2,7-Dibromo-9-mesityl-10-methylacridinium tetrafluoroborate
909181 2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate
909254 2,7-Difluoro-9-mesityl-10-methylacridinium tetrafluoroborate
909319 2,7-Dibromo-10-methylacridone, ≥95%
909327 2,7-Dimethoxy-9-mesityl-10-methylacridinium tetrafluoroborate

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