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900432 Sigma-Aldrich

Tetra-n-butylammonium decatungstate

Synonym: 1-Butanaminium, N,N,N-tributyl-, eicosa-μ-oxodi-μ5-oxodecaoxodecatungstate (4:1), 1-Butanaminium, N,N,N-tributyl-, salt with tungstic acid (4:1), TBADT, Tetrakis(N,N,N-tributyl-1-butanaminium) tungstate, Tetrakis(tetrabutylammonium) decatungstate

  • CAS Number 68109-03-5

  • Empirical Formula (Hill Notation) C64H144N4O32W10

  • Molecular Weight 3320.24

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Other Catalysts, Photocatalysis, Tungsten Catalysts More...
Quality Level   100
form   powder
reaction suitability   reagent type: catalyst

Description

Application

When used in conjunction with cobaloxime pyridine chloride (341630), this complex can effect the catalytic, room-temperature dehydrogenation of unactivated alkanes under solar irradiation with hydrogen as the sole byproduct.

Packaging

250 mg in glass bottle

Other Notes

Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis

C(sp3)–H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Dehydrogenation through Cooperative Base Metal Catalysis

The mild dehydrogenation of unactivated small molecules presents a formidable challenge for synthetic chemists. The Sorensen group has recently reported a dual-catalytic system capable of dehydrogena...
Keywords: Catalysis, Dehydrogenation, Oxidations

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