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900570 Sigma-Aldrich

Ir[dF(t-Bu)-ppy]3

  • CAS Number 1380203-57-5

  • Empirical Formula (Hill Notation) C45H42F6IrN3

  • Molecular Weight 931.04

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts, Photocatalysis
Quality Level   100
form   powder or crystals
mp   370.93 °C
reaction suitability   reagent type: catalyst
reaction type: Photocatalysis
SMILES string   FC1=CC([Ir]2(C3=C4C(F)=CC(F)=C3)([N]5=C4C=C(C(C)(C)C)C=C5)([N]6=C7C=C(C(C)(C)C)C=C6)[N]8=C(C9=C2C=C(F)C=C9F)C=C(C(C)(C)C)C=C8)=C7C(F)=C1

Description

Application

Ir[dF(t-Bu)-ppy]3 is a photocatalyst that readily facilitates the decarboxylative arylation of α-amino acids using visible light.

Packaging

50 mg in glass bottle

Citation

Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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Description

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901368 [Ir(dFppy)2(dtbbpy)]PF6
901409 [Ir(dF(Me)ppy)2(dtbbpy)]PF6
904694 Ir(p-CF3-ppy)3, ≥95%
905097 Ir(p-Me-ppy)3
905100 Ir(p-tBu-ppy)3
905917 (Ir[Me(Me)ppy]2(dtbpy))PF6

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