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900624 Sigma-Aldrich

Di-t-butyl oxaziridine

≥95%

Synonym: Kurti oxaziridine

  • CAS Number 56741-77-6

  • Empirical Formula (Hill Notation) C9H19NO

  • Molecular Weight 157.25

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Properties

Related Categories C-X Bond Formation (Non-Halogen), Chemical Synthesis, Other Non-Halogen Reagents for C-X Bond Formation, Synthetic Reagents
assay   ≥95%
form   liquid
refractive index   n/D 1.4453
density   0.90 g/mL
storage temp.   2-8°C

Description

Application

This oxaziridine has been used in synthetic methods for amination, heteroatom transfer, and C-H functionalization. Recently, the lab of Laszlo Kurti demonstrated its application for direct electrophilic primary and secondary amination of arylmetals in the presence of Cu(I) salts -- void of precious metal catalysts, ligands, protecting groups, or directing groups.

Other Notes

Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals

Rapid heteroatom transfer to arylmetals utilizing multifunctional reagent scaffolds

Diverse sp3 C-H functionalization through alcohol β-sulfonyloxylation

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis

Protocols & Articles

Articles

Laszlo Kurti Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Laszlo Kurti Group - Professor Product Portal
Keywords: Agrochemicals, Aminations, Arylations, Building blocks, C-C bond formation, Catalysis, Grignard Reaction, Medicinal chemistry, Organic synthesis, Pharmaceutical

Peer-Reviewed Papers
15

References

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