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901197 Sigma-Aldrich

(t-Bu)2PhP Pd G3

95%

Synonym: Methanesulfonato (di-tert-butyl) phenylphosphino (2′-amino-1,1′-biphenyl-2-yl) palladium(II), PPh(t-Bu)2-Pd-G3

  • CAS Number 2230788-65-3

  • Empirical Formula (Hill Notation) C27H36NO3PPdS

  • Molecular Weight 592.04

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Properties

Related Categories Buchwald 3rd Generation Palladacycles, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling More...
Quality Level   100
assay   95%
form   solid
reaction suitability   reagent type: catalyst
reaction type: Cross Couplings
mp   163-169 °C (decomp.)
SMILES string   CC(C)(C)P(C(C)(C)C)C1=CC=CC=C1.NC2=C(C3=C([Pd]OS(C)(=O)=O)C=CC=C3)C=CC=C2
InChI   1S/C14H23P.C12H10N.CH4O3S.Pd/c1-13(2,3)15(14(4,5)6)12-10-8-7-9-11-12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h7-11H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key   IQWMOOOMAPPAMZ-UHFFFAOYSA-M

Description

Other Notes

Third-generation Buchwald precatalyst.

Safety & Documentation

Safety Information

WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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