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901216 Sigma-Aldrich

(S)-Ph-quinox

≥95%

Synonym: (S)-4-Phenyl-2-(quinolin-2-yl)-4,5-dihydrooxazole

  • CAS Number 1252576-13-8

  • Empirical Formula (Hill Notation) C18H14N2O

  • Molecular Weight 274.32

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Properties

Related Categories C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis, Ligands and Auxiliaries
Quality Level   100
assay   ≥95%
form   powder or crystals
reaction suitability   reagent type: ligand
reaction type: C-H Activation
mp   142 °C

Description

Application

(S)-Ph-quinox is a chiral dinitrogen ligand which is used in the iridium-catalyzed enantioselective borylation and silylation of aromatic C-H bonds, in addition to the enantioselective palladium-catalyzed diamination of alkenes. It can also be used in the aza-Wacker-type cyclization reaction of the olefinic tosylamides with molecular oxygen.

Other Notes

Enantioselective palladium-catalyzed diamination of alkenes using N-fluorobenzenesulfonimide

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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Description

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809128 (R)-Ph-Quinox

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