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901368 Sigma-Aldrich

[Ir(dFppy)2(dtbbpy)]PF6

  • CAS Number 1072067-44-7

  • Empirical Formula (Hill Notation) C40H36F10IrN4P

  • Molecular Weight 985.92

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts, Photocatalysis
Quality Level   100
form   powder or crystals
mp   >300 °C
reaction suitability   reagent type: catalyst
reaction type: Photocatalysis

Description

Application

This photocatalyst readily facilitates alkynylation of carboxylic acids as well as the decarboxylative cross-coupling of oxalates via metallaphotoredox catalysis.

Other Notes

• Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3-sp2 Cross-Coupling of Oxalates with Aryl Halides.
• Room-Temperature Decarboxylative Alkynylation of Carboxylic Acids Using Photoredox Catalysis and EBX Reagents.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

Related Products

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Product #

Description

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900540 Ir(dFppy)3
900539 Ir[p-F(t-Bu)-ppy]3
900538 Ir(p-F-ppy)3
900570 Ir[dF(t-Bu)-ppy]3
901409 [Ir(dF(Me)ppy)2(dtbbpy)]PF6
902217 Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902225 Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%
904694 Ir(p-CF3-ppy)3, ≥95%
905518 Ir(dFFppy)2(dtbbpy)PF6
905917 (Ir[Me(Me)ppy]2(dtbpy))PF6
908568 [Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6, ≥95%
908703 [Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%
747769 [Ir(dtbbpy)(ppy)2]PF6
747793 (Ir[dF(CF3)ppy]2(dtbpy))PF6
804215 [Ir{dFCF3ppy}2(bpy)]PF6

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