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901443 Sigma-Aldrich

Trimethylphosphine solution

1.0 M in 2-methyltetrahydrofuran

Synonym: PMe3, Trimethylphosphane, Trimethylphosphorus

  • CAS Number 594-09-2

  • Linear Formula (CH3)3P

  • Molecular Weight 76.08

  •  Beilstein Registry Number 969138

  •  MDL number MFCD00008510

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
InChI Key   YWWDBCBWQNCYNR-UHFFFAOYSA-N
form   liquid
concentration   1.0 M in 2-methyltetrahydrofuran
density   0.838 g/mL
reaction suitability   reagent type: ligand
reaction type: Mitsunobu Reaction
  reagent type: ligand
reaction type: Wittig Reaction

Description

Application

Trimethylphosphine is an electron-rich phosphine ligand used in the Mitsunobu reaction. It participates in the transformation of azides into carbamates, aziridines from azidoalcohols, iminophosphoranes and aza-Wittig reaction. This product is offered as a solution in 2-methyltetrahydrofuran for more convenient handling.

Safety & Documentation

Safety Information

RIDADR 
UN 1993BF 3 / PGII

Documents

Certificate of Analysis

Protocols & Articles
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Description

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