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904694 Sigma-Aldrich

Ir(p-CF3-ppy)3

≥95%

  • CAS Number 500295-52-3

  • Empirical Formula (Hill Notation) C36H21F9IrN3

  • Molecular Weight 858.77

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts, Photocatalysis
assay   ≥95%
form   powder or crystals
mp   >300 °C
reaction suitability   reagent type: catalyst
reaction type: Photocatalysis

Description

Application

This photocatalyst facilitates a variety of transformations using visible light, including the defluorination of arenes.

Other Notes

Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis

Photocatalytic C–F alkylation; facile access to multifluorinated arenes

Safety & Documentation

Safety Information

WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

Related Products

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Product #

Description

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900540 Ir(dFppy)3
900539 Ir[p-F(t-Bu)-ppy]3
900538 Ir(p-F-ppy)3
900570 Ir[dF(t-Bu)-ppy]3
900579 (S)-2-Benzylpiperidine, ≥95%
901466 Mes-Umemoto reagent, ≥95%
901368 [Ir(dFppy)2(dtbbpy)]PF6
901409 [Ir(dF(Me)ppy)2(dtbbpy)]PF6
902217 Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902225 Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902489 Tris(trimethylsilyl)silanol, ≥95%
905097 Ir(p-Me-ppy)3
905100 Ir(p-tBu-ppy)3
747769 [Ir(dtbbpy)(ppy)2]PF6
747793 (Ir[dF(CF3)ppy]2(dtbpy))PF6
804215 [Ir{dFCF3ppy}2(bpy)]PF6

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