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904716 Sigma-Aldrich

(CAAC-Cy)Rh(COD)Cl

Synonym: [2-[2,6-bis(1-methylethyl)phenyl]-3,3-dimethyl-2-azaspiro[4.5]dec-1-ylidene]chloro[(1,2,5,6-η)-1,5-cyclooctadiene]Rhodium

  • CAS Number 1801869-83-9

  • Empirical Formula (Hill Notation) C31H47ClNRh

  • Molecular Weight 572.07

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts More...
form   powder or crystals
storage temp.   −20°C

Description

Application

(CAAC-Cy)Rh(COD)Cl is a selective hydrogenation catalyst used for the hydrogenation of a variety of arenes including fluoroarenes giving access to all-cis-multifluorinated cycloalkanes.1

Other Notes

Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes

Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes

Safety & Documentation

Safety Information

WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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683108 (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I), 99%

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