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905534 Sigma-Aldrich

(2-(Phenoxycarbonyl)phenyl)boronic acid

≥95%

  • CAS Number 2211934-51-7

  • Empirical Formula (Hill Notation) C13H11BO4

  • Molecular Weight 242.04

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Catalysis and Inorganic Chemistry, Chemical Synthesis,
assay   ≥95%
form   powder or crystals
mp   150-152 °C
reaction suitability   reagent type: catalyst
storage temp.   2-8°C

Description

Application

(2-(Phenoxycarbonyl)phenyl)boronic acid is a boronic acid catalyst from the Hall Group developed for chemoselective activation of oxime N−OH bonds for the preparation of functionalized amide compounds via Beckmann Rearrangement. This catalyst is efficient to transform various diaryl, aryl-alkyl, heteroaryl-alkyl, and dialkyl oximes to amide products under ambient conditions.

Other Notes

Scope and Mechanism of a True Organocatalytic Beckmann Rearrangement with a Boronic Acid/Perfluoropinacol System under Ambient Conditions

Safety & Documentation

Safety Information

Safety Information for this product is unavailable at this time.

Documents

Certificate of Analysis

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Protocols & Articles
Peer-Reviewed Papers
15

References

Related Products

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Product #

Description

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683809 2-Methoxycarbonylphenylboronic acid, ≥95.0%
683833 2-Ethoxycarbonylphenylboronic acid, ≥95%

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