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  • 905917 - (Ir[Me(Me)ppy]2(dtbpy))PF6

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905917 Sigma-Aldrich

(Ir[Me(Me)ppy]2(dtbpy))PF6

  • CAS Number 1607469-49-7

  • Empirical Formula (Hill Notation) C44H48F6IrN4P

  • Molecular Weight 970.06

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts, Photocatalysis
form   powder
reaction suitability   reagent type: catalyst
reaction type: Photocatalysis
SMILES string   F[P-](F)(F)(F)(F)F.CC1=CC([Ir+]([N]2=C3C=C(C)C=C2)(C4=C5C=CC(C)=C4)([N]6=C7C=C(C(C)(C)C)C=C6)([N]8=C7C=C(C(C)(C)C)C=C8)[N]9=C5C=C(C)C=C9)=C3C=C1

Description

Application

(Ir[Me(Me)ppy]2(dtbpy))PF6 or Ir(dmppy)2(dtbbpy)PF6 is an iridium photoredox catalyst that facilitates a variety of transformations using visible light, including the α- and β-alkylation of aldehydes.

Other Notes

Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis

Direct, enantioselective α-alkylation of aldehydes using simple olefins

Safety & Documentation

Safety Information

WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

Related Products

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Product #

Description

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900540 Ir(dFppy)3
900539 Ir[p-F(t-Bu)-ppy]3
900538 Ir(p-F-ppy)3
900570 Ir[dF(t-Bu)-ppy]3
900579 (S)-2-Benzylpiperidine, ≥95%
901466 Mes-Umemoto reagent, ≥95%
901368 [Ir(dFppy)2(dtbbpy)]PF6
901409 [Ir(dF(Me)ppy)2(dtbbpy)]PF6
902217 Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902225 Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902489 Tris(trimethylsilyl)silanol, ≥95%
747769 [Ir(dtbbpy)(ppy)2]PF6
747793 (Ir[dF(CF3)ppy]2(dtbpy))PF6
804215 [Ir{dFCF3ppy}2(bpy)]PF6

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