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905925 Sigma-Aldrich

[Pd(terpy)(2-Cl-phen)](BF4)2

≥95%

Synonym: Ritter fluorination catalyst

  • CAS Number 2133345-76-1

  • Empirical Formula (Hill Notation) C27H18B2ClF8N5Pd

  • Molecular Weight 727.95

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
assay   ≥95%
form   powder or crystals
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
mp   >300 °C
storage temp.   2-8°C
SMILES string   ClC(C=C1)=NC2=C1C=CC3=CC=C[N]([Pd]45[N]6=C(C7=CC=CC=[N]75)C=CC=C6C8=CC=CC=[N]84)=C32

Description

Application

[Pd(terpy)(2-Cl-phen)](BF4)2 was developed in the Ritter lab for the elecrophilic fluorination of arenes.

Other Notes

Palladium-catalysed electrophilic aromatic C-H fluorination

Legal Information

This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH (US Patent Pending 16/083,160 and PCT/US2017/021563).

Safety & Documentation

Safety Information

WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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Description

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905879 [Pd(terpy)(MeCN)][BF4]2, ≥95%

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