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908568 Sigma-Aldrich

[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6

≥95%

Synonym: [5,5′-Bis(trifluoromethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate

  • CAS Number 1973375-72-2

  • Empirical Formula (Hill Notation) C36H16F22IrN4P

  • Molecular Weight 1145.69

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts, Photocatalysis
assay   ≥95%
form   powder or crystals
mp   >300 °C

Description

Application

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations including the alkylation of remote C-H bonds and alkene aminoarylation.

Other Notes

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

Arylsulfonylacetamides as bifunctional reagents for alkene aminoarylation

Safety & Documentation

Safety Information

WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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902217 Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902225 Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%
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747793 (Ir[dF(CF3)ppy]2(dtbpy))PF6
804215 [Ir{dFCF3ppy}2(bpy)]PF6

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