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908703 Sigma-Aldrich

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

≥95%

Synonym: [(4,4′-di-tert-butyl-2,2′-bipyridine)-bis-(5-methyl-2-(5-fluoro-phenyl)-pyridine)-iridium(III)] hexafluorophosphate

  • CAS Number 808142-88-3

  • Empirical Formula (Hill Notation) C42H42F8IrN4P

  • Molecular Weight 977.99

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts, Photocatalysis
assay   ≥95%
form   powder or crystals

Description

Application

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.

Other Notes

Direct, enantioselective α-alkylation of aldehydes using simple olefins

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds

Decarboxylative sp3 C-N coupling via dual copper and photoredox catalysis

Safety & Documentation

Safety Information

WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

Related Products

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Description

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901368 [Ir(dFppy)2(dtbbpy)]PF6
901409 [Ir(dF(Me)ppy)2(dtbbpy)]PF6
902217 Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902225 Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%
747769 [Ir(dtbbpy)(ppy)2]PF6
747793 (Ir[dF(CF3)ppy]2(dtbpy))PF6
804215 [Ir{dFCF3ppy}2(bpy)]PF6

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