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912794 Sigma-Aldrich

Ni(COD)(DQ)

New

≥95%

Synonym: Bis(1,5-cyclooctadiene)(duroquinone) nickel(0)

  • CAS Number 40759-64-6

  • Empirical Formula (Hill Notation) C18H24NiO2

  • Molecular Weight 331.08

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Properties

Related Categories Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, New Products for Chemical Synthesis, Nickel,
Quality Level   100
assay   ≥95%
form   powder
mp   227 °C (decomposition)

Description

Application

Ni(COD)(DQ), as shown by the Engle lab, is an air- and thermally stable Ni(0) precatalyst. This 18-electron complex has a unique stability profile allowing for easy reaction setup outside an inert atmosphere. Transformations such as the Suzuki-Miyaura coupling, borylation of aryl halides, and alkene hydroarylation have been demonstrated.

Other Notes

Ni(COD)(DQ): An Air-Stable 18-Electron Ni(0)–Olefin Precatalyst

Safety & Documentation

Safety Information

Safety Information for this product is unavailable at this time.

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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244988 Bis(1,5-cyclooctadiene)nickel(0)
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