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912948 Sigma-Aldrich

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

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  • CAS Number 2222402-20-0

  • Empirical Formula (Hill Notation) C44H34F20IrN4P

  • Molecular Weight 1221.93

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Description

Application

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the α-arylation of alcohols.

Other Notes

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis

Safety & Documentation

Safety Information

WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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901409 [Ir(dF(Me)ppy)2(dtbbpy)]PF6
902217 Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902225 Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%
905518 Ir(dFFppy)2(dtbbpy)PF6

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