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94866 Sigma-Aldrich

Boc-α-(4-bromobenzyl)-DL-Pro-OH

≥96.0% (HPLC)

Synonym: 1-Boc-2-(4-bromobenzyl)-2-pyrrolidinecarboxylic acid, Boc-α-(4-bromobenzyl)-DL-proline

  • CAS Number 336817-91-5

  • Empirical Formula (Hill Notation) C17H22BrNO4

  • Molecular Weight 384.26

  •  MDL number MFCD03095429

  •  PubChem Substance ID 57653645

  •  NACRES NA.22

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Properties

Related Categories Chemical Biology, Chemical Synthesis, Peptide Synthesis and Peptide Chemistry, Proline Derivatives, Unnatural Amino Acids & Derivatives More...
Quality Level   100
assay   ≥96.0% (HPLC)
form   powder
application(s)   peptide synthesis: suitable
color   off-white
SMILES string   CC(C)(C)OC(=O)N1CCCC1(Cc2ccc(Br)cc2)C(O)=O
InChI   1S/C17H22BrNO4/c1-16(2,3)23-15(22)19-10-4-9-17(19,14(20)21)11-12-5-7-13(18)8-6-12/h5-8H,4,9-11H2,1-3H3,(H,20,21)
InChI key   VQWRXYZZPMLJRL-UHFFFAOYSA-N

Description

Packaging

500 mg in poly bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles

Articles

Cyclic Aryl-Substitued Amino Acid Derivatives

Aromatic a-substituted proline analogs and g-substituted pyroglutamates are valuable building blocks in both medicinal and peptide chemistry. Through Suzuki coupling technology, they can be used as s...
ChemFiles Volume 1 Article 1
Keywords: Building blocks, Peptidomimetics, Suzuki coupling

Proline Derivatives and Analogs

Proline is a non-polar proteinogenic amino acid that forms a tertiary amide when incorporated into peptides. It does not have a hydrogen on the amide group and therefore cannot act as a hydrogen bond...
Chemfiles Volume 5 Article 12
Keywords: Adhesion, Biochemistry, Catalysis, Deposition, Hydroxylations, Isomerizations, Nucleic acid hybridization, Pharmaceutical, Reductions, Substitutions, Type

Proline Derivatives

Proline is a non-polar, natural amino acid that forms a tertiary amide when incorporated into peptides. Thus, it is the only proteinogenic amino acid that does not act as a hydrogen bond donor in a p...
Matthias Junkers
Aldrich ChemFiles 2008, 8.7, 8.
Keywords: Asymmetric synthesis, Chemfiles, Pharmaceutical

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