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B73104 Sigma-Aldrich

1-Bromonaphthalene

97%

  • CAS Number 90-11-9

  • Empirical Formula (Hill Notation) C10H7Br

  • Molecular Weight 207.07

  •  Beilstein/REAXYS Number 1906414

  •  EC Number 201-965-2

  •  MDL number MFCD00003868

  •  PubChem Substance ID 24891985

  •  NACRES NA.22

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Properties

Related Categories Aryl, Building Blocks, C9 to C12, Chemical Synthesis, Halogenated Hydrocarbons,
Quality Level   200
assay   97%
refractive index   n20/D 1.6570 (lit.)
bp   133-134 °C/10 mmHg (lit.)
mp   −2-−1 °C (lit.)
density   1.48 g/mL at 20 °C (lit.)
SMILES string   Brc1cccc2ccccc12
InChI   1S/C10H7Br/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
InChI key   DLKQHBOKULLWDQ-UHFFFAOYSA-N

Description

Application

1-Bromonaphthalene is a bromoarene that can be used in:
• Palladium-catalyzed Suzuki–Miyaura coupling reaction with potassium aryltrifluoroborates without the use of phase-transfer catalysts or phosphine ligands.
• The preparation of indeno annelated polycyclic aromatic hydrocarbons by reacting with o-bromobenzeneboronic acid and oligocyclic bromoarenes via Suzuki-Heck type coupling.
• Ni catalyzed Kumada–Tamao–Corriu cross-coupling reaction with PhMgBr.
• The preparation of arylnaphthalenes via palladium-catalyzed Suzuki-Miyaura cross-coupling reaction with aryl boronic acid.

Packaging

5, 100, 500 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
RTECS 
QJ1545000
Flash Point(F) 
230.0 °F - closed cup
Flash Point(C) 
110 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles

Protocols

Preparation of High Refractive Index Films on PET Substrates

Zirconium bromonorbornanelactone carboxylate triacrylate (PRM30) is a zirconium-containing multifunctional acrylate useful for producing cured, transparent films with high refractive indices. It can ...
Keywords: Positron Emission Tomography, Solvents

Peer-Reviewed Papers
15

References

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