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  • C2107 - (1S)-(+)-10-Camphorsulfonic acid

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C2107 Sigma-Aldrich

(1S)-(+)-10-Camphorsulfonic acid

99%

Synonym: (+)-Camphor-10-sulfonic acid (β), (1S)-Camphor-10-sulfonic acid

  • CAS Number 3144-16-9

  • Empirical Formula (Hill Notation) C10H16O4S

  • Molecular Weight 232.30

  •  Beilstein/REAXYS Number 2809675

  •  EC Number 221-554-1

  •  MDL number MFCD00064157

  •  PubChem Substance ID 24892465

  •  NACRES NA.22

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Properties

Related Categories Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks,
assay   99%
optical activity   [α]20/D +19.9°, c = 2 in H2O
mp   196-200 °C (dec.) (lit.)
SMILES string   CC1(C)[C@@H]2CC[C@@]1(CS(O)(=O)=O)C(=O)C2
InChI   1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
InChI key   MIOPJNTWMNEORI-GMSGAONNSA-N

Description

Application

(1S)-(+)-10-Camphorsulfonic acid may be used as a starting material to synthesize 10-iodocamphor. It may also be used as a dopant to induce chirality in the conduction band of polyaniline. (±)-S-methyl-S-phenylsulfoximine can be resolved using it as a chiral resolving agent to form the (-)-form in high enantiomeric purity.

Used as a resolving agent, as a catalyst for coupling dipeptides.

Packaging

5, 100, 500 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2585PSN2 8 / PGIII
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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