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C22415 Sigma-Aldrich

4-Chloroaniline

98%

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Properties

Related Categories Amines, Building Blocks, C6, Chemical Synthesis, Nitrogen Compounds - Organic Building Blocks,
vapor density   4.4 (vs air)
vapor pressure   0.15 mmHg ( 25 °C)
InChI Key   QSNSCYSYFYORTR-UHFFFAOYSA-N
assay   98%
form   chips
  crystals or chunks
bp   232 °C(lit.)
mp   67-70 °C (lit.)

Description

Application

4-Chloroaniline can undergo:
• Allylation in the presence of ultrasonication to form N-allyl-4-chloroaniline, a precursor for bioactive compounds containing indole and dihydroindole nucleus.
• Povarov reaction with cyclopentadiene to form C-2 aliphatic substituted tetrahydroquinolines.
• Mannich reaction with aldehydes and cyclic ketones to form β-amino carbonyl compounds.
• Nitration to form 4-chloro-3-nitroaniline in the presence of guanidinium nitrate.

Packaging

5, 100, 500 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2018 6.1 / PGII
WGK Germany 
3
RTECS 
BX0700000
Flash Point(F) 
248 °F
Flash Point(C) 
120 °C

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles
Peer-Reviewed Papers
15

References

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