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D62004 Sigma-Aldrich

cis-1,2-Dichloroethylene

97%

Synonym: cis-1,2-DCE, cis-Acetylene dichloride

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Properties

Related Categories Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
InChI Key   KFUSEUYYWQURPO-UPHRSURJSA-N
assay   97%
refractive index   n20/D 1.449 (lit.)
bp   60 °C(lit.)
mp   −80 °C (lit.)
density   1.284 g/mL at 25 °C (lit.)

Description

Application

cis-1,2-Dichloroethylene (cis-1,2-DCE) is generally used in the preparation of various enediynes for Bergman cyclization. Applications include the synthesis of:
• 2-(6-substituted 3(Z)-hexen-1,5-diynyl)anilines to prepare corresponding substituted carbazoles.
• (Z)-1-aryl-3-henen-1,5-diynes to obtain the corresponding aryl substituted benzotriazoles.


It is used as a linker to synthesize boron-dipyrromethene (BODIPY)-based photosensitizer for photodynamic therapy (PDT). cis-1,2-DCE can also be used as a precursor to synthesize intermediates of sporolide B.

Packaging

1, 10, 50 g in ampule

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN1150 - class 3 - PG 2 - 1,2-Dichloroethylene
WGK Germany 
2
RTECS 
KV9420000
Flash Point(F) 
42.8 °F
Flash Point(C) 
6 °C

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles
Peer-Reviewed Papers
15

References

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accessory

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