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T45004 Sigma-Aldrich

Triallylamine

99%

Synonym: TAA

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Properties

Related Categories Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks More...
vapor density   4.73 (vs air)
vapor pressure   90 mmHg ( 80 °C)
InChI Key   VPYJNCGUESNPMV-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.451(lit.)
bp   150-151 °C(lit.)
density   0.79 g/mL at 25 °C(lit.)

Description

Packaging

1 L in glass bottle

250 mL in glass bottle

Application

• Triallylamine (TAA) reacts with primary aromatic amines in the presence of a ruthenium catalyst to form 2-ethyl-3-methylquinolines.
• TAA undergoes hydrozirconation followed by transmetalation with germanium tetrachloride to form 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane. This compound can react with Grignard or lithium reagents to form the corresponding 5-organo compounds.
• The cycloaddition of TAA to fluorinated 1,3,4-oxadiazoles affords octahydro-2,7-methanofuro[3,2-c]pyridines.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2610 8(3) / PGIII
WGK Germany 
3
RTECS 
XX5950000
Flash Point(F) 
87.8 °F
Flash Point(C) 
31 °C

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Protocols & Articles
Peer-Reviewed Papers
15

References

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