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ALD00230 Sigma-Aldrich

Sodium 4,4-difluorocyclohexanesulfinate

Synonym: Baran DFHS-Na Reagent

  • Empirical Formula (Hill Notation) C6H9F2NaO2S

  • Molecular Weight 206.19

  •  MDL number MFCD28124334

  •  PubChem Substance ID 329772643

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Properties

Related Categories Baran Diversinates, C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis, Fluorinated Cyclic Diversinates,
InChI Key   YVVCXFAMBAWLEV-UHFFFAOYSA-M
form   powder
mp   290-295 °C

Description

Packaging

1, 10 g in glass bottle

500 mg in glass bottle

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Other Notes

Radical-Based Regioselective C-H Functionalization of Electron-Deficient Heteroarenes: Scope, Tunability, and Predictability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Diversinates™: Any-Stage Functionalization of (Hetero)aromatic Scaffolds

The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. With the ever-growing demand of new chemical entities coupled to the dwindling resources and time cons...
Keywords: Alkylations, Catalysis, Chemical industry, Cross couplings, PAGE

Professor Product Portal - Baran Group

From our library of Articles, Sigma-Aldrich presents Professor Product Portal - Baran Group
Keywords: Building blocks, Fluorinations, Oxidations, Pharmaceutical

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