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ALD00348 Sigma-Aldrich

Boc-3-[3,4-bis(trifluoromethyl)phenyl]-L-alanine

≥95% (HPLC)

Synonym: (S)-3-(3,4-Bis(trifluoromethyl)phenyl)-2-(tert-butoxycarbonylamino)propanoic acid

  • CAS Number 2120095-23-8

  • Empirical Formula (Hill Notation) C16H17F6NO4

  • Molecular Weight 401.30

  •  PubChem Substance ID 329772653

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C-H Activation, Catalysis and Inorganic Chemistry, Chemical Biology, Chemical Synthesis,
Quality Level   100
description   ALPH: +24.0, 0.5%EtOH
assay   ≥95% (HPLC)
form   powder or solid
application(s)   peptide synthesis: suitable
reaction suitability   reagent type: ligand
reaction type: C-H Activation
storage temp.   2-8°C
SMILES string   OC([C@@H](NC(OC(C)(C)C)=O)CC1=CC(C(F)(F)F)=C(C(F)(F)F)C=C1)=O
InChI   1S/C16H17F6NO4/c1-14(2,3)27-13(26)23-11(12(24)25)7-8-4-5-9(15(17,18)19)10(6-8)16(20,21)22/h4-6,11H,7H2,1-3H3,(H,23,26)(H,24,25)/t11-/m0/s1
InChI key   LLRXWQAYIGATCH-NSHDSACASA-N

Description

Application

Unnatural amino acid was derived from a C-H Activation methodology developed by Jin-Quan Yu and coworkers. The Pd-mediated C-C bond formation can be made in tandem with 2-Methylpyridine (Aldrich 109835).

Packaging

1 g in glass bottle

Other Notes

Ligand-Controlled C(sp3)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
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