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ALD00352 Sigma-Aldrich

Boc-2-methoxy-L-phenylalanine

97%

Synonym: (S)-2-(tert-butoxycarbonylamino)-3-(2-methoxyphenyl)propanoic acid

  • CAS Number 143415-63-8

  • Empirical Formula (Hill Notation) C15H21NO5

  • Molecular Weight 295.33

  •  MDL number MFCD01860640

  •  PubChem Substance ID 329772655

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C-H Activation, Catalysis and Inorganic Chemistry, Chemical Biology, Chemical Synthesis,
Quality Level   100
assay   97%
form   powder
application(s)   peptide synthesis: suitable
mp   157 °C
reaction suitability   reagent type: ligand
reaction type: C-H Activation
storage temp.   2-8°C
SMILES string   OC([C@@H](NC(OC(C)(C)C)=O)CC1=CC=CC=C1OC)=O
InChI   1S/C15H21NO5/c1-15(2,3)21-14(19)16-11(13(17)18)9-10-7-5-6-8-12(10)20-4/h5-8,11H,9H2,1-4H3,(H,16,19)(H,17,18)/t11-/m0/s1
InChI key   QMHKMTAKTUUKEK-NSHDSACASA-N

Description

Application

Unnatural amino acid was derived from a C-H Activation methodology developed by Jin-Quan Yu and coworkers. The Pd-mediated C-C bond formation can be made in tandem with 2-Methylpyridine (Aldrich 109835).

Packaging

1 g in glass bottle

Other Notes

Ligand-Controlled C(sp3)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
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