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ALD00386 Sigma-Aldrich

Fe(dibm)3

Synonym: Baran Olefin Cross-Coupling Catalyst, Iron tris(diisobutyrylmethane)

  • CAS Number 24444-72-2

  • Empirical Formula (Hill Notation) C27H45FeO6

  • Molecular Weight 521.49

  •  PubChem Substance ID 329772664

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron, Non-Precious Metal Catalysis
Quality Level   100
reaction suitability   core: iron
  reagent type: catalyst
mp   96-102 °C
SMILES string   O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.[Fe+3]
InChI   1S/3C9H15O2.Fe/c3*1-6(2)8(10)5-9(11)7(3)4;/h3*5-7H,1-4H3;/q3*-1;+3
InChI key   LKNJSJQVZKKQHU-UHFFFAOYSA-N

Description

Application

Iron tris(diisobutyrylmethane) was reported by Baran and coworkers to be an effective catalyst in the cross-coupling of olefins. In the presence of phenylsilane (Aldrich 335150), several highly substituted and novel functionalized C-C bonds can be formed using simple and mild reaction conditions.

Packaging

100 mg in glass bottle

Other Notes

The Baran Laboratory Blog: Functionalized Olefin Cross-Coupling

Functionalized olefin cross-coupling to construct carbon–carbon bonds

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Professor Product Portal - Baran Group

From our library of Articles, Sigma-Aldrich presents Professor Product Portal - Baran Group
Keywords: Building blocks, Fluorinations, Oxidations, Pharmaceutical

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