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ALD00430 Sigma-Aldrich

1-Naphthalenyl ester fluorosulfuric acid

  • CAS Number 133042-64-5

  • Empirical Formula (Hill Notation) C10H7FO3S

  • Molecular Weight 226.22

  •  PubChem Substance ID 329772677

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Sulfates/Sulfites, Sulfur Compounds More...
Quality Level   100
description   Fp: >230°F
form   liquid
refractive index   n20/D 1.5576
density   1.3674 g/mL at 25 °C
SMILES string   O=S(OC1=CC=CC2=CC=CC=C21)(F)=O
InChI   1S/C10H7FO3S/c11-15(12,13)14-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
InChI key   GEZWNEDYJCOWLU-UHFFFAOYSA-N

Description

Application

The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperature and are not air sensitive.

Packaging

500 mg in glass bottle

Other Notes

Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
RIDADR 
UN 3265 8 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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