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ALD00562 Sigma-Aldrich

2,3-Dibromo-propylamine, hydrobromide

  • CAS Number 6963-32-2

  • Empirical Formula (Hill Notation) C3H8Br3N

  • Molecular Weight 297.81

  •  MDL number MFCD00666060

  •  PubChem Substance ID 329772720

  •  NACRES NA.22

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Properties

Related Categories Bromination, C-C Bond Formation, C-X Bond Formation (Halogen), Chemical Synthesis, Other Synthetic Reagents for C-C Bond Formation,
Quality Level   100
reaction suitability   reaction type: C-C Bond Formation
SMILES string   BrCC(Br)CN.[H]Br
InChI   1S/C3H7Br2N.BrH/c4-1-3(5)2-6;/h3H,1-2,6H2;1H
InChI key   NQVQUJRBCVAMIL-UHFFFAOYSA-N

Description

Application

In tandem with Turbo Grignard (Aldrich product 656984) and an electrophilic trap, 2,3-Dibromo-propylamine hydrobromide generates a "spring loaded" electrophile, which is a convenient reagent for the installation of azetidine to secondary amines. This product is one of several synthetic useful reagents reported by Baran and coworkers on Strain-release amination.

Packaging

1 g in glass bottle

Other Notes

Strain-release amination

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Professor Product Portal - Baran Group

From our library of Articles, Sigma-Aldrich presents Professor Product Portal - Baran Group
Keywords: Building blocks, Fluorinations, Oxidations, Pharmaceutical

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