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  • ALD00574 - (1R,4R)-1-((4-(Trifluoromethyl)phenyl)sulfonyl)bicyclo[2.1.0]pentane, (-)-R-enantiomer

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ALD00574 Sigma-Aldrich

(1R,4R)-1-((4-(Trifluoromethyl)phenyl)sulfonyl)bicyclo[2.1.0]pentane, (-)-R-enantiomer

95%

  • CAS Number 2074732-95-7

  • Empirical Formula (Hill Notation) C12H11F3O2S

  • Molecular Weight 276.27

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Other Synthetic Reagents for C-C Bond Formation, Synthetic Reagents
Quality Level   100
assay   95%
form   powder or chunks (crystals)
reaction suitability   reaction type: C-C Bond Formation

Description

Application

The following "spring-loaded" electrophile is a convenient reagent for the installation of cyclopentane to primary and secondary amines. This product is one of several synthetically useful reagents reported by Baran and coworkers for the “any-stage” installation of small, strained ring systems.

Packaging

100, 250 mg in glass insert

Other Notes

Strain-release amination
Strain-Release Heteroatom Functionalization: Development, Scope, and Stereospecificity

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Professor Product Portal - Baran Group

From our library of Articles, Sigma-Aldrich presents Professor Product Portal - Baran Group
Keywords: Building blocks, Fluorinations, Oxidations, Pharmaceutical

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