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ALD01822 Sigma-Aldrich

4-((2,3-dimethylbutan-2-yl)amino)benzamide

  •  PubChem Substance ID 329772800

  •  NACRES NA.22

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Properties

Related Categories Baran Hindered Amines, Building Blocks, Chemical Synthesis, Organic Building Blocks
SMILES string   CC(C(C)C)(C)NC1=CC=C(C(N)=O)C=C1

Description

Application

Traditionally challenging to access, this hindered amine provides a chemically differentiated building block for organic synthesis and medicinal chemistry, specifically for preparation of drug candidates containing hindered amine motifs. Additionally, this and over 80 other sterically hindered secondary amines in the Sigma-Aldrich portfolio provide structurally distinct screening compounds. Screen several through Aldrich Market Select. This hindered amine was accessed via a recent publication reported by Baran and coworkers using an innovative hydroamination method.

Other Notes

Product of KemXTree

Practical olefin hydroamination with nitroarenes

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Professor Product Portal - Baran Group

From our library of Articles, Sigma-Aldrich presents Professor Product Portal - Baran Group
Keywords: Building blocks, Fluorinations, Oxidations, Pharmaceutical

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ALD01636 3-methyl-3-((4-(methylthio) phenyl)amino) butan-1-ol
ALD01638 4-(methylthio)-N-(2, 4, 4 trimethylpentan-2-yl)aniline
ALD01640 N-(2,3-dimethylbutan-2-yl)-4-(methylthio) aniline
ALD01642 N-(4-(tert-butylamino)phenyl) acetamide
ALD01648 3-methyl-3-((perfluorophenyl) amino)butan-1-ol
ALD01650 3-methyl-3-(naphthalen-1-ylamino) butan-1-ol
ALD01652 2-methoxy-N-(1-methylcyclohexyl) pyridin-3-amine
ALD01654 3-((2-methoxypyridin-3-yl) amino)-3-methylbutan-1-ol
ALD01656 4-methoxy-N-(2,4,4-trimethyl pentan-2-yl)aniline
ALD01658 3-((2-chlorophenyl) amino)-3-methylbutan-1-ol
ALD01660 3-((9H-fluoren-2-yl)amino)-3-methylbutan-1-ol
ALD01662 N-(4-(benzyloxy)-2-methylbutan-2-yl)-9H-fluoren-2-amine
ALD01666 N-(2-methylpentan-2-yl)pyridin-3-amine
ALD01668 4-methoxy-N-(2-methylpentan-2-yl)aniline
ALD01670 3-methyl-3-((4-(trifluoromethyl)phenyl)amino)butan-1-ol
ALD01672 N-(1-(benzyloxy)-2-methylpropan-2-yl)-4-(trifluoromethyl)aniline
ALD01674 N-(1-(benzyloxy)-2-methylpropan-2-yl)-4-bromoaniline
ALD01676 3-((4-bromophenyl)amino)-3-methylbutan-1-ol
ALD01678 N-(4-(benzyloxy)-2-methylbutan-2-yl)-4-bromoaniline
ALD01680 4-bromo-N-(2,3-dimethylbutan-2-yl)aniline
ALD01682 4-bromo-N-(tert-pentyl)aniline
ALD01684 3-((4-methoxyphenyl)amino)-3-methylbutan-1-ol
ALD01686 N-(2,3-dimethylbutan-2-yl)-4-methoxyaniline
ALD01688 4-methoxy-N-(tert-pentyl)aniline
ALD01690 3-methyl-3-(m-tolylamino)butan-1-ol
ALD01692 N-(4-(benzyloxy)-2-methylbutan-2-yl)-3-methylaniline
ALD01694 N-(2,3-dimethylbutan-2-yl)-3-methylaniline
ALD01696 3-methyl-N-(tert-pentyl)aniline
ALD01698 3-methyl-N-(1-methylcyclohexyl)aniline
ALD01700 3-((3-bromophenyl)amino)-3-methylbutan-1-ol
ALD01702 N-(4-((4-hydroxy-2-methylbutan-2-yl)amino)phenyl)acetamide
ALD01704 N-(3-((2,3-dimethylbutan-2-yl)amino)phenyl)acetamide
ALD01706 N-(1,1,2-trimethylpropyl)-(4-N-acetyl)-benzenamine
ALD01708 3-methyl-N-(2,4,4-trimethylpentan-2-yl)aniline
ALD01710 4-methoxy-N-(1-methylcyclohexyl)aniline
ALD01712 3-((3-N-acetylphenyl)amino)-3-methylbutan-1-ol
ALD01714 3-(N-acetyl)-N-(2-methylpentan-2-yl)aniline
ALD01716 3-(N-acetyl)-N-(1-methylcyclohexyl)aniline
ALD01718 4-(N-acetyl)-N-(tert-pentyl)aniline
ALD01720 4-(N-acetyl)-N-(2-methylpentan-2-yl)aniline
ALD01722 1-naphtyl-N-(1-methylcyclohexyl)aniline
ALD01726 4-((1-hydroxy-3-methybutan-3-yl)amino)phenyltrifluoromethanesulfonate
ALD01728 4-((2-methypentan-2-yl)amino)phenyltrifluoromethanesulfonate
ALD01730 3-methyl-2-(methylphenyl-1-ylamino)butan-1-ol
ALD01732 2-methylphenyl-N-(1-methylcyclohexyl)aniline
ALD01734 3-((3-methoxypyridin-2-yl)amino)-3-methylbutan-1-ol
ALD01736 3-(N-acetyl)-N-(tert-pentyl)aniline
ALD01738 N-(1,1-dimethylbutyl)-1-naphthalenamine
ALD01740 N-(1,1,3,3-tetramethylbutyl)-1-naphthalenamine
ALD01742 N-(1,1-dimethylethyl)-1-Naphthalenamine
ALD01744 2-methoxy-5-methyl-N-(1-hydroxy-3-methylbutan-3-yl)aniline
ALD01748 3-((4-bromo-3-(trifluoromethyl)phenyl)amino)-3-methylbutan-1-ol
ALD01758 N-(4-(benzyloxy)-2-methylbutan-2-yl)-4-chloroaniline
ALD01760 N-(4-((4-hydroxy-2-methylbutan-2-yl)amino)-2-methylphenyl)acetamide
ALD01766 N-(tert-butyl)-4-methoxyaniline
ALD01768 N-(1-(benzyloxy)-2-methylpropan-2-yl)-2-chloroaniline
ALD01772 4-(tert-butylamino)phenyl trifluoromethanesulfonate
ALD01774 N-(tert-butyl)-2-methylaniline
ALD01776 2-methoxy-5-methyl-N-(2,4,4-trimethylpentan-2-yl)aniline
ALD01780 N-(tert-butyl)-4-(methylthio)aniline
ALD01782 2-methoxy-N-(2,4,4-trimethylpentan-2-yl)pyridin-3-amine
ALD01784 N-(tert-butyl)-2-methoxypyridin-3-amine
ALD01786 N-(tert-butyl)-9H-fluoren-3-amine
ALD01790 N-(2-methyl-4-((1-methylcyclohexyl)amino)phenyl)acetamide
ALD01796 N-(tert-butyl)-4-chloroaniline
ALD01798 4-chloro-N-(2,3-dimethylbutan-2-yl)aniline
ALD01800 4-chloro-N-(1-methylcyclohexyl)aniline
ALD01802 4-chloro-N-(tert-pentyl)aniline
ALD01804 3-((4-chlorophenyl)amino)-3-methylbutan-1-ol
ALD01806 4-fluoro-N-(2,4,4-trimethylpentan-2-yl)aniline
ALD01808 4-fluoro-N-(1-methylcyclohexyl)aniline
ALD01810 N-(2,3-dimethylbutan-2-yl)-4-fluoroaniline
ALD01812 4-fluoro-N-(tert-pentyl)aniline
ALD01814 4-fluoro-N-(2-methylpentan-2-yl)aniline
ALD01816 3-methyl-N-(2-methylpentan-2-yl)aniline
ALD01818 4-(tert-butylamino)benzamide
ALD01824 N-(1-methylcyclohexyl)-9H-fluoren-3-amine
ALD01830 N-(1-(benzyloxy)-2-methylpropan-2-yl)-4-fluoroaniline
ALD01832 4-((2-methylpentan-2-yl)amino)benzamide
ALD00588 N-(1-methylcyclohexyl)-4-(methylthio)aniline
ALD00590 N-(3-(tert-butylamino)phenyl)acetamide
803952 4-((1-methylcyclohexyl)amino)phenyl trifluoromethanesulfonate
803979 4-((1-(benzyloxy)-2-methylpropan-2-yl)amino)phenyl trifluoromethanesulfonate
803960 3-((3,5-difluorophenyl) amino)-3-methylbutan-1-ol
803987 N-(4-(benzyloxy)-2-methylbutan-2-yl)-2-chloroaniline
804096 N-(4-((1-methylcyclohexyl)amino) phenyl)acetamide

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