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CF0002 Sigma-Aldrich

1-Fluoro-3,3-dimethylbenziodoxole

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Properties

Related Categories Chemical Synthesis, Fluorination Reagents, Perfluoroalkylation, Synthetic Reagents
form   solid

Description

Application

1-Fluoro-3,3-dimethylbenziodoxole is a crystalline, off-white solid which can be handled under air for extended periods without noticeable hydrolytic decomposition. In the presence of excess fluoride ions (provided by triethylamine-hydrogen fluoride complexes), it can effectively function as an electrophilic fluorination reagent for easily enolizable diketo substrates, or it can engage in silver catalyzed difluorination of styrenes.

Other Notes

Technology Spotlight: Fluoroalkylation: Expansion of Togni Reagents

Legal Information

Product of CF Plus Chemicals.

Safety & Documentation

Safety Information

Symbol 
GHS03  GHS03
Signal word 
Danger
Hazard statements 
Precautionary statements 
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Fluoroalkylation: Expansion of Togni Reagents

The installation of highly fluorinated groups into drug and pesticide candidates is a powerful strategy to modulate their properties. An incorporated fluorinated sidechain can tune the acidobasic beh...
Keywords: Catalysis, Chlorinations, Cyclizations, Degradations, Fluorinations, Grignard Reaction, Pesticides, Radical cyclization

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