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D36550 Sigma-Aldrich

Dibenzyl phosphate

99%

Synonym: DBzP

  • CAS Number 1623-08-1

  • Linear Formula (C6H5CH2O)2P(O)(OH)

  • Molecular Weight 278.24

  •  Beilstein/REAXYS Number 2055755

  •  EC Number 216-602-3

  •  MDL number MFCD00004775

  •  PubChem Substance ID 24893773

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds More...
Quality Level   100
assay   99%
mp   78-80 °C (lit.)
storage temp.   2-8°C
SMILES string   OP(=O)(OCc1ccccc1)OCc2ccccc2
InChI   1S/C14H15O4P/c15-19(16,17-11-13-7-3-1-4-8-13)18-12-14-9-5-2-6-10-14/h1-10H,11-12H2,(H,15,16)
InChI key   HDFFVHSMHLDSLO-UHFFFAOYSA-N

Description

Application

Dibenzyl phosphate (DBzP) can be used:
• To promote the monoselective ortho-C-H alkylation of N-quinolyl benzamides with primary and secondary alkyl iodides.
• For the ring-opening reaction of epoxide such as benzylglycidol to synthesize dihydroxyacetone phosphate (DHAP).
• As a reactant for the synthesis of stereospecific 1,2-trans glycosyl phosphates.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

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Protocols & Articles
Peer-Reviewed Papers
15

References

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